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HI84532-02 Mini Titrator for Measuring Titratable Acidity in Fruit Juice

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The HI84532 is a simple, fast, and affordable automatic mini titrator designed for testing the acidity of fruit juice. Based on an acid base titration method, this mini titrator uses an optimized preprogrammed method of analysis with a powerful algorithm that determines the completion of the titration reaction by the use of a glass body pH electrode.

The HI84532 incorporates a precision piston style dosing pump that adjusts the volume of titrant dosed dynamically based on a voltage change. This dosing system reduces the amount of time required for the titration while providing for a highly accurate determination of the amount of titrant used.

This mini titrator is supplied complete with all the materials necessary to perform low and high range measurements of titratable acidity in fruit juice. Results are displayed as % citric acid, tartaric acid and malic acid. All chemicals are premixed and prepackaged including standardized titrants, reagents and pump calibration solution. There is no need for volumetric glassware or analytical balances making titrations fast and easy to perform.

  • Piston driven pump for accurate dynamic dosing
  • Complete with glass double junction pH electrode
  • Pre-standardized titrant and pre-measured reagents

Titratable acidity is an important parameter in determining fruit maturity and sour taste in citrus fruits. The maturity of fruit is one of the most important factors to determine how well fruit will store and how it will taste. For some fruits, governmental quality standards (based on titratable acidity or the ratio of total soluble solids (°Brix) to titratable acidity) are in place to protect consumers. Immature fruit will normally have a low sugar to acid ratio as compared to mature fruit that will have a high sugar to acid ratio.

The HI84532 measures the concentration of titratable hydrogen ions contained in fruit juice samples by neutralization with a strong base solution to a fixed pH. This value includes all the substances of an acidic nature in the fruit juice including: free hydrogen ions, organic acids and acid salts. Titratable acidity is expressed as g/100 mL of the predominant acid. The predominant acids in fruit depend on the type of fruit being tested and include citric acid, tartaric acid, and malic acid. 

 

juice acid types and titratable acidity

 

 
Double Junction pH Electrode

The HI84532 is supplied with the HI1131B refillable, double junction, combination pH electrode. By design, the HI1131B has a spherical tip for use in aqueous or liquid solutions. This versatile electrode provides a wide surface of contact with a sample and is ideal for direct measurements or titrations in the beverage industry.

Custom pH Calibration

According to AOAC International the titration endpoint for fruit products is pH 8.1. The HI84532 uses a custom calibration point of pH 8.20. The preprogrammed pH 4.01 and pH 8.20 calibration points allows for calibration of the meter that brackets the pH readings.

Good Laboratory Practice

The HI84532 offers comprehensive GLP information including date and time of the last pH electrode and dosing pump calibrations. Tracking calibrations are critical to have confidence in the results obtained from titrations. The GLP data is stored along with any logged readings.

Piston Driven Dosing Pump

The heart of the HI84532 is the piston driven burette pump. This type of dosing system uses a motor in which each dose is very precisely controlled and the volume dispensed is accurately determined. This titrant is dynamically dosed, where titrant is delivered in larger doses at the start of the titration and smaller doses near the end point. With larger doses in the beginning of the titration, the speed of the titration is increased, where smaller doses near the end point allow for more time for the titrant and analyte to react. Smaller doses also prevent the over titration of a sample and a more accurate determination of titrant volume used.

Automatic Stirrer

The built-in stirrer is automatically maintained at a speed of 600 rpm, regardless of the viscosity of the solution being titrated.


On-screen Features

titrator screenshot

Easy-to-Use Interface The HI84532 has an intuitive user design with clearly defined keys and a large screen that is easy to navigate. The meter has a built-in tutorial mode that, when enabled, will walk the user step by step through the titration process. A dedicated HELP key is always available to allow access to content-specific information during both calibration and titration.

warning

Procedure Warnings Users are warned if there is an error in procedures such as the titration exceeded the maximum volume of titrant.

mini titrator acidity graphic mode

Graphic Mode This mini titrator displays in-depth data during titration, including a real-time graph of the titration curve.

mini titrator acidity logging

Log-on-Demand

The HI84532 allows for data logging of up to 400 samples: 200 titration results and 200  pH/mV readings. Data can be stored and exported to a USB drive or a PC using the USB connection. 

mini titrator pH mv meter

pH/mV Meter In addition to being an automatic titrator, the HI84532 also can be used as a pH/mV meter. As a pH meter, it has many features of a professional grade benchtop including automatic calibration up to three points with four available buffers, a 0.01 pH resolution, accuracy of ±0.01 pH, automatic temperature compensation and comprehensive GLP data.

mini titrator acidity graphic mode

CAL Check Accuracy is always ensured with Hanna’s unique CAL Check feature, which analyzes the response of the electrode during the calibration process. Based on electrode response in the buffer, indicators are displayed on screen to alert the user of potential problems during calibration. These indicators include Buffer Contaminated, Electrode Dirty/Broken, and overall probe condition. The CAL Check function not only ensures an accurate pH reading when the HI84532 is used as a pH meter, but also an accurate titration since the endpoint of a titratable acidity titration is determined by a set pH value.

 

SKU HI84532-02
Product Name Mini Titrator for Measuring Titratable Acidity in Fruit Juice - HI84532
Quote Required Yes
pH-mV Range -2000.0 to 2000.0 mV
pH-mV Resolution 0.1 mV
pH-mV Accuracy ±1.0 mV (@25ºC/77ºF)
pH Range -2.0 to 16.0 pH; -2.00 to 16.00 pH
pH Resolution 0.1 pH / 0.01 pH
pH Accuracy ±0.01 pH (@25ºC/77ºF)
pH Calibration one, two, or three-point calibration, four available buffers (4.01, 7.01, 8.20, 10.01)
pH Temperature Compensation manual or automatic
Temperature Range -20.0 to 120.0°C; -4.0 to 248.0°F; 253.2 to 393.2 K
Temperature Resolution 0.1°C; 0.1°F; 0.1K
Temperature Accuracy ±0.4°C; ±0.8°F; ±0.4 K (@25ºC/77ºF), without probe error
Titration Method acid base titration
Titration Principle endpoint titration
Titration Range Low Range (g/100 mL)
Titration Resolution 0.01%
Titration Accuracy ±0.02% or 3% of reading CA whichever is greater (@25ºC/77ºF)
Sample Size Low Range
Titration Pump Speed 10 mL/min
pH Electrode HI1131B glass body, refillable, with BNC connector and 1 m (3.3’) cable (included)
Temperature Probe HI7662-T stainless steel temperature probe with 1 m (3.3’) cable (included)
Logging Type Log-on-demand
Logging Memory up to 400 ( 200 titrations, 200 pH/mV readings)
Connectivity 1 USB port for data storage and export to a PC
Built-in Magentic Stirrer Built-in magnetic stirrer at 600 rpm
Power Supply 12 VDC adapter (included)
Environment 0 to 50°C (32 to 122°F); RH max 95% non-condensing
Dimensions 235 x 200 x 150 mm (9.2 x 7.9 x 5.9”)
Weight 1.9 kg (67.0 oz.)
Ordering Information HI84532 is supplied with HI1131B pH electrode, HI84532-50 low range titrant (100 mL), HI84532-51 high range titrant (100 mL), HI84532-55 calibration standard (100 mL), HI7662-T temperature probe, HI7082 electrode fill solution (30 mL), 100 mL beakers (2), 20 mL beaker, tube set (aspiration tube with titrant bottle cap and dispensing tube with tip), dosing pump valve, 5 mL syringe, 1 mL plastic pipette, stir bar, power adapter, instruction manual and quality certificate.

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